Additions to C-X &pgr;-Bonds, Part 1, Volume 1 by S.L. Schreiber PDF

By S.L. Schreiber

ISBN-10: 0080405924

ISBN-13: 9780080405926

Quantity 1 offers an in depth survey of reactions that entail the 1,2-addition of nonstabilized carbanion equivalents of carbonyl, imino and thiocarbonyl performance. Emphasis has been put on these reagents that lead to hugely selective addition reactions. tools are suggested to choose, for instance, one carbonyl team over one other within the similar molecule, or so as to add preferentially a fraction to at least one (enantiotopic of diastereotopic) face of a carbonyl crew. approaches that end result from an preliminary addition to the C=X practical crew, for instance alkenations and rearrangements, also are coated during this quantity.

Show description

Read Online or Download Additions to C-X &pgr;-Bonds, Part 1, Volume 1 PDF

Similar organic chemistry books

Download PDF by John A. Joule, Alan R. Katritzky, Christopher A. Ramsden,: Handbook of Heterocyclic Chemistry (3rd Edition)

Heterocyclic compounds play an essential function within the metabolism of residing cells. Their useful functions diversity from large scientific use to fields as diversified as agriculture, images, biocide formula and polymer science.

Written through best students and specialists, the instruction manual of Heterocyclic Chemistry is carefully up-to-date with over 50% new content material. it's been rewritten with a brand new accelerated writer staff, who've conscientiously distilled crucial details at the reactivity, constitution and synthesis of heterocycles from the 2008 significant reference paintings finished Heterocyclic Chemistry III. To convey the paintings modern the writer crew have additionally extra new man made examples and constructions, key functions and new references from 2008-2010.

Contains greater than 1500 in actual fact drawn constructions and reactions. The hugely systematic assurance given to the topic makes this some of the most authoritative single-volume debts of contemporary heterocyclic chemistry to be had and will be beneficial reference for these instructing a heterocyclic course.

-Covers the constitution, reactivity and synthesis of all heterocyclic compounds as distilled from the bigger 15-volume reference paintings -Saves researchers time once they require very important info on heterocycles--speeding them to hundreds of thousands of sincerely drawn chemical buildings and pertinent experiences by means of best specialists -Features 35% new fabric to go with the thoroughly revised text

Quality: Vector, Searchable, Bookmarked

Download e-book for kindle: Analytical Pyrolysis of Natural Organic Polymers by S.C. Moldoveanu

Analytical pyrolysis is without doubt one of the many instruments applied for the research of typical natural polymers. This books describes in 3 components the method of analytical pyrolysis, the result of pyrolysis for a number of biopolymers, and several other useful functions of analytical pyrolysis on usual natural polymers and their composite fabrics.

Additional info for Additions to C-X &pgr;-Bonds, Part 1, Volume 1

Sample text

J. 15, 243–249 (1998). 34. , Zhang, H. , Reuter, V. , Hamilton, W. , Lloyd, K. , and Livingston, P. , Int. J. Cancer 73, 42–49 (1997). 35. Park, T. , Kim, I. , Bilodeau, M. , Randolph, J. , and Danishefsky, S. , J. Am. Chem. Soc. 118, 11488–11500 (1996). 36. , Park, T. , Kim, I. , Lloyd, K. , Danishefsky, S. , and Livingston, P. , Angew. , Int. Ed. 36, 125–128 (1997). 37. , Slovin, S. , Kim, I. , Kim, H. , Bornmann, W. , Lloyd, K. , Scher, H. , Livingston, P. , and Danishefsky, S. , Angew. , Int.

Moreover, it allows for facile recycling of the polymer support for further use once the final carbohydrate assemblage is cleaved from the resin. 4 Polymer support silylene linking method for hindered hydroxyl-bearing glycals. 5 Glycals loaded via silylene linkage. mono-halogenated counterpart. This differential in reactivity allows for a single linkage of more sterically demanding systems in the first stage, while discouraging 2-fold silylation (see 11→12). A more reactive nucleophile, such as a primary alcohol, even if polymer bound, can now join at the less active remaining silylating site.

8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. , Top. Curr. Chem. 186, 65–86 (1996); (h) Danishefsky, S. , and Roberge, J. , in Glycopeptides and Related Compounds: Synthesis, Analysis and Applications, Large, D. , and Warren, C. D. ), Marcel Dekker; New York, 1997, p. 245 and references therein; (i) Seeberger, P. , and Danishefsky, S. , Acc. Chem. Res. 31, 685–695 (1998). Halcomb, R. , and Danishefsky, S. , J. Am. Chem. Soc. 111, 6661–6666 (1989). , J. Chem. Soc. Chem.

Download PDF sample

Additions to C-X &pgr;-Bonds, Part 1, Volume 1 by S.L. Schreiber


by John
4.1

Rated 4.76 of 5 – based on 37 votes

About admin